Effective rotational Hamiltonian of the
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Qing-shi Zhu
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Article
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1992
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Elsevier Science
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English
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The effective rotational Hamiltonians of the local mode states are derived for XY,, XY, and XY4 molecules by averaging the vibration-rotation Hamiltonians using the corresponding local mode vibrational wavefunctions. The results indicate that in a local mode vibrational state the molecular symmetry