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Transformation of the effective rotational Hamiltonian of nonrigidX2Ymolecules

โœ Scribed by V. I. Starikov; Vl. G. Tyuterev


Book ID
110147335
Publisher
SP MAIK Nauka/Interperiodica
Year
2000
Tongue
English
Weight
85 KB
Volume
88
Category
Article
ISSN
0030-400X

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Effective rotational Hamiltonian of the
โœ Qing-shi Zhu ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 384 KB

The effective rotational Hamiltonians of the local mode states are derived for XY,, XY, and XY4 molecules by averaging the vibration-rotation Hamiltonians using the corresponding local mode vibrational wavefunctions. The results indicate that in a local mode vibrational state the molecular symmetry