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Effect of vibrational excitation of HBr on the H+HBr abstraction and exchange reactions

✍ Scribed by Jozef Tiňo; Ján Urban; Viliam Klimo

Book ID
104792603
Publisher
Springer
Year
1988
Tongue
English
Weight
510 KB
Volume
74
Category
Article
ISSN
1432-2234

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QCT study of isotopic effects in H + HBr
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✍ Jozef Tiňo; Ján Urban; Viliam Klimo 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 303 KB

## Abstract The method of quasi‐classical trajectories on an LEPS hypersurface was used for studying the influence of the exchange of one or both of the hydrogen atoms for deuterium in the reaction H^1^ + H^2^Br. As expected, the reaction cross sections of the exchange and abstraction reactions wer

On the mechanism of the reaction K + HBr
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A potential-energy surface with a low barrier in the exit valley can account for large isotope effects observed in the reaction of K with FrEW, DBr or TBr. Reaction is confined to a range of incident angles determined by the reactant translational and vibrational energies.