Chemical Dynamics of H Abstraction by OH Radicals: Vibrational Excitation of H 2 O, HOD, and D 2 O Produced in Reactions of OH and OD with HBr and DBr
โ Scribed by Butkovskaya, N. I.; Setser, D. W.
- Book ID
- 120541631
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 609 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
A lower limit to t?re OH(X a 11) vibrational escitation produced by the reaction O(r D) + Ha has been obsewed using a low-pressure infrared chemilumiuescence anoaratus. The O(' D) was generated by laser photolysis of OS\_ The measured \_\* OH(v') vibrational distribution is inverted; it peaks at U'
Rotational and vibrational state distributions of the OH radicals produced in the reaction 160( I D) "at" H21So ~ x6OH + IsOH have been determined using a laser-induced fluorescence technique. 160(ID) was prepared by the 193 nm photodissociation of N20. The rotational distributions for 16OH and 1sOH
Photofrngment fluorescence, from OH and OD(A 2Z++ X 'U), has been observed following two-photon excitation of Hz0 and D20 in the gas phase with a KrF laser (248 nmj The rotational band contour of the OH fluorescence is the same as that observed folIowing single-photon vacuum ultrawolet photolysis of