## Abstract The copolymerization kinetics of conventional emulsions and miniemulsions of 50:50 and 25:75 molar ratios vinyl acetate–butyl acrylate monomer mixtures were studied using sodium hexadecyl sulfate as surfactant. Hexadecane was the cosurfactant used in the preparation of the miniemulsions
Effect of the conformation of the alkyl chain on the catalytic miniemulsion copolymerization of ethylene and acrylates
✍ Scribed by Sorin N. Sauca; Amaia Agirre; Ralph C. Even; José M. Asua
- Book ID
- 116455781
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 462 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0014-3057
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📜 SIMILAR VOLUMES
Emulsion and miniemulsion copolymerizations were carried out with acrylic monomers (methyl methacrylate, butyl acrylate, and acrylic acid) in the presence of a n alkyd resin. Poly(methy1 methacrylate) was used as a hydrophobe or cosurfactant in the miniemulsion reactions. The results demonstrate tha
## Abstract Pulsed‐laser polymerization (PLP) has been adopted by IUPAC as the method of choice for the determination of propagation rate constants (__k__~p~). However, the method has failed in the polymerization of alkyl acrylates at temperatures above 30 °C. In this work, the PLP experiments were