## Abstract Miniemulsion stability of threeβcomponent disperse phase systems comprising styrene [ST (1)], methyl methacrylate [MMA (2)], and stearyl methacrylate [SMA (3)] was investigated. The Ostwald ripening rate (Ο) increases with increasing MMA content in the monomer mixture. The empirical equ
Miniemulsion copolymerizations of methyl methacrylate and butyl acrylate in the presence of reactive costabilizer
β Scribed by C. T. Lin; W. Y. Chiu; H. C. Lu; Y. Meliana; C. S. Chern
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 140 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0021-8995
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The effect of a chain-transfer agent (CTA) on the kinetics and molecular weight distribution of the methyl methacrylate/butyl acrylate semicontinuous emulsion polymerization was investigated. The dodecanethiol had a slight effect on the reaction rate but significantly affected the secondary nucleati
Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme