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Effect of temperature on the ageing behaviour of unsaturated ester-based lubricants

✍ Scribed by Zhang, X. ;Murrenhoff, H. ;Weckes, P. ;Hölderich, W.

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
459 KB
Volume
21
Category
Article
ISSN
0265-6582

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✦ Synopsis

Abstract

The ageing behaviour of trimethylolpropane trioleate was investigated at different temperatures in a modified rotary bomb test apparatus. Some physicochemical properties of ageing oil samples, such as acid value, kinematic viscosity, and iodine value, were measured. The oil samples were analysed using gas chromatography, gas chromatography‐mass spectrometry, and gel permeation chromatography to assess the influence of temperature on the ageing behaviour of ester‐based oils. The results revealed that an increase in temperature could greatly speed up the ageing reaction and increase the formation of decomposition products. However, the degree of oil ageing remained similar when the same quantity of oxygen was consumed.

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