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Effect of substituted methyl group on the main-chain scission of alkyl radical in solid

โœ Scribed by Tsuneki Ichikawa


Book ID
108046401
Publisher
Elsevier Science
Year
1992
Weight
354 KB
Volume
40
Category
Article
ISSN
1359-0197

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Xanthates as Chain-Transfer Agents in Co
โœ Mathias Destarac; Wojciech Bzducha; Daniel Taton; Isabelle Gauthier-Gillaizeau; ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 118 KB

## Abstract The capability of three chainโ€transfer agents, __O__โ€alkylโ€__S__โ€(1โ€ethoxycarbonyl)ethyl xanthates (CH~3~CHCO~2~C~2~H~5~)S(C๏ฃพS)OZโ€ฒ, to control the freeโ€radical polymerization of styrene and ethyl acrylate by the MADIX process was examined. The reactivity of the xanthates varied accordin