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Hindered internal rotation of the methyl group in .alpha.-substituted ethyl radicals. Effect of fluorine

โœ Scribed by Chen, Kuang S.; Kochi, Jay K.


Book ID
126068317
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
845 KB
Volume
96
Category
Article
ISSN
0002-7863

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Hindered internal rotation in methyl n-m
โœ S.van der Werf; J.B.F.N. Engberts ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Recently we reported that the NMR spectra of the alkyl N-methyl-N-arylsulfonylmethylcarbamates I -III showed only temperature dependence of the signal of the ester alkyl group (1). It was suggested that the barrier to internal rotation merely involved the ester group itself since the data then avail