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AM1 studies on alkyl and allyl radical additions to methyl-substituted ethenes and on the β-bond scissions of the radicals formed

✍ Scribed by T Körtvélyesi


Book ID
113257744
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
803 KB
Volume
277
Category
Article
ISSN
0166-1280

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Abstmct -A new general synthesis of y-subshtuted y-lactones and Gsubstltuted &lactones including dlhydro-5 octyl-2(3H)-furanone, a natural pheromone, 1s described The synthesis involves the regloselectlve j3-sclsslon of alkoxyl ra&cals generated from transannular hemlacetals as the key step Substitu