๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Effect of solvent polarity on the rate of ozone reaction with unsaturated compounds

โœ Scribed by M. Gomes; S. D. Razumovskii; G. E. Zaikov

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
202 KB
Volume
16
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

โœฆ Synopsis

The effect of the polarity of seven solvents (c = 2-60) on the rate of ozone reactions with stilbene and ally1 chloride has been studied. The data show that the rate of the reaction is insensitive to the medium polarity. The results of earlier publications are revised and are shown to be in agreement with the present data.

๐Ÿ“œ SIMILAR VOLUMES

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of ozone with unsaturated oxygenates
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB ๐Ÿ‘ 2 views

The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f

The rate of reaction of methyl radicals
The rate of reaction of methyl radicals with ozone
โœ E. A. Ogryzlo; R. Paltenghi; Kyle D. Bayes ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 388 KB ๐Ÿ‘ 1 views

## Abstract The absolute rate constant for the reaction of methyl radicals with ozone has been measured as a function of temperature. Small concentrations of CH~3~ were generated by flash photolyzing CH~3~NO~2~ at 193 nm with an ArF laser. A photoionization mass spectrometer was used to follow the

Kinetics and Mechanisms for the Reaction
Kinetics and Mechanisms for the Reactions of Ozone with Unsaturated Oxygenated Compounds
โœ Dr. Ismael Al Mulla; Dr. Lisa Viera; Dr. Rebecca Morris; Prof. Howard Sidebotto ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 239 KB ๐Ÿ‘ 1 views

## Abstract Rate coefficients for the reaction of ozone with a series of unsaturated oxygenated compounds are determined in air at atmospheric pressure and (298ยฑ3) K. Rate data are obtained using both relative and absolute rate techniques, and the measured rate coefficients are found to be in good

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of Ozone with unsaturated Aliphatic Alcohols
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 431 KB ๐Ÿ‘ 1 views

The gas-phase reaction of ozone with unsaturated alcohols in air has been investigated a t atmospheric pressure and ambient temperature (288-291 K). Cyclohexane was added to scavenge the hydroxyl radical which forms as a product of the ozone-unsaturated alcohol reaction. The reaction rate constants,

Solvent effects on the rate of reaction
Solvent effects on the rate of reaction of Cl2ห™โˆ’ and SO4ห™โˆ’ radicals with unsaturated alcohols
โœ Z. B. Alfassi; S. Padmaja; P. Neta; R. E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 405 KB ๐Ÿ‘ 1 views

## Abstract Rate constants have been measured in several aqueous/organic solvent mixtures for the addition reaction of Cl~2~^ห™โˆ’^ radicals with 2โ€propenโ€1โ€o1 and 2โ€butenโ€1โ€o1 as a function of temperature and with 2, 3โ€dimethylโ€2โ€butene at room temperature. The rate constants were in the range of 10^