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Effect of solvation on the reactivity of ion pairs

✍ Scribed by Shinohara, Makoto.; Smid, Johannes.; Szwarc, Michael.

Book ID
127115624
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
307 KB
Volume
90
Category
Article
ISSN
0002-7863

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Stabilization of ionβ€”molecule pairs by s
Stabilization of ionβ€”molecule pairs by solvation
✍ M. Ben-Nun; R.D. Levine πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 639 KB

Efficient V-T energy transfer between the vibrational mode of an ionic species and its salvation shell -seen in full molecular dynamics simulations -is interpreted in terms of a model Hamiltonian. The impulse-lie transfer is shown to result from a vibrationally non-adiabatic energy exchange.