Stabilization of ion—molecule pairs by solvation

✍ Scribed by M. Ben-Nun; R.D. Levine

• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 639 KB
• Volume: 214
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(93)90077-e

✦ Synopsis

Efficient V-T energy transfer between the vibrational mode of an ionic species and its salvation shell -seen in full molecular dynamics simulations -is interpreted in terms of a model Hamiltonian. The impulse-lie transfer is shown to result from a vibrationally non-adiabatic energy exchange.