Solvation of ion pairs with poly(ethylene oxide)
β Scribed by G. N. Arkhipovich; Ye. A. Ugolkova; K. S. Kazanskii
- Book ID
- 104690481
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 428 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
The interaction of sodium, potassium and caesium salts with poly(ethylene oxide) in nitromethane is considered as a model for solvation of alkali counterions with a heterochain polymer during the anionic polymerization of heterocycles. The methods of 23Na and 133Cs n.m.r, and of conductometry sensit
Efficient V-T energy transfer between the vibrational mode of an ionic species and its salvation shell -seen in full molecular dynamics simulations -is interpreted in terms of a model Hamiltonian. The impulse-lie transfer is shown to result from a vibrationally non-adiabatic energy exchange.