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Effect of PVC on low-polar isobutylene polymerization in the presence of BCl3

✍ Scribed by Luděk Toman; Rudolf Lukáš; Jiří Spěváček; Petr Holler

Publisher
Springer
Year
1995
Tongue
English
Weight
397 KB
Volume
34
Category
Article
ISSN
0170-0839

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Thermally induced polymerization of isobutylene in the presence of SnCl4: Kinetic study of the polymerization and NMR structural investigation of low molecular weight products
✍ Luděk Toman; Jiří Spěváček; Petr Vlček; Petr Holler 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 2 views

The polymerization reactivity of isobutylene/SnCl 4 mixtures in the absence of polar solvent, was investigated in a temperature interval from Ϫ78 to 60 °C. The mixture is nonreactive below Ϫ20 °C but slow polymerization proceeds from Ϫ20 to 20 °C with the initial rate r 0 of the order 10 Ϫ5 mol ⅐ l