Thermally induced polymerization of isob
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Luděk Toman; Jiří Spěváček; Petr Vlček; Petr Holler
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Article
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2000
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John Wiley and Sons
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English
⚖ 229 KB
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The polymerization reactivity of isobutylene/SnCl 4 mixtures in the absence of polar solvent, was investigated in a temperature interval from Ϫ78 to 60 °C. The mixture is nonreactive below Ϫ20 °C but slow polymerization proceeds from Ϫ20 to 20 °C with the initial rate r 0 of the order 10 Ϫ5 mol ⅐ l