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Living carbocationic polymerization of isobutylene with BCl3coinitiation in the presence of di-tert-butylpyridine as proton trap

✍ Scribed by Lajos Balogh; Rudolf Faust


Publisher
Springer
Year
1992
Tongue
English
Weight
321 KB
Volume
28
Category
Article
ISSN
0170-0839

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Living cationic polymerization of styren
✍ Oh-Sig Kwon; Chang Gi Gho; Byong-Seok Choi; Sam-Kwon Choi 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 393 KB

## Abstract The polymerization of styrene was studied by using a bifunctional initiator, 1,4‐bis(1‐chloroethyl)benzene (1). It was demonstrated that living polymerization can be achieved in the styrene/1/SnCl~4~ system in chloroform at −15°C in the presence of 2,6‐di‐__tert__‐butylpyridine. The num