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Effect of pressure on the formation of the intramolecular excited complex state in 4-(9-anthrylmethyl)-N,N-dimethylaniline

✍ Scribed by Kimihiko Hara; Kazuyuki Obara

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 229 KB
Volume: 117
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80412-7

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✦ Synopsis

The formation of an intramolecular excited complex stale in 4-(9-anthrylmeLhyl)-N.N-dimeLhylaniline was investigated at h@ p-w_ A change in the kinetics from thermodyoamic conlrol to kinetic control VIZ observed m ethyl elhcr solvent In loluene tie pr-is kinclically con~olled over the whole pressure range. Appearance of tis pr-depends upon the solvcn~ viscosity. suggesting a conformahonal change in the wurse of the formation of Abe excited complex slate

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