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Effect of pressure on rate and equilibrium in nucloephilic addition to mesityl oxide

✍ Scribed by Scott, Julian J.; Brower, Kay R.

Book ID
126220367
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
436 KB
Volume
89
Category
Article
ISSN
0002-7863

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## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for