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Effect of molecular structure on stereoselectivity during the hydrolysis of diastereoisomeric permethrinic acid esters

✍ Scribed by Kalmál Simon; Irén Boros; Gyula Balogh; György Hidasi; Elemér Fogassy; Ferenc Faigl; Mária Ács


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
735 KB
Volume
161
Category
Article
ISSN
0022-2860

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Effects of structural variations on the
✍ Munir N. Nassar; Bushra J. Agha; George A. Digenis 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 420 KB

The effect of structural variations on the rates of elastase-catalyzed hydrolysis of model carbonate and carbamate esters was studied using HPLC. It is shown that branching in the immediate vicinity of the carbonate or carbamate functionally results in decreased hydrolysis rates. Whereas aryl carbon