Effect of ions on the IR spectra of several primary and secondary aliphatic amines
β Scribed by T. E. Pavlova; I. S. Pominov
- Publisher
- Springer US
- Year
- 1969
- Tongue
- English
- Weight
- 285 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0021-9037
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π SIMILAR VOLUMES
Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce
Tltc fluorescence and p~ospharesc~nce of some aliphstic amine8 have been measured. A rcmnrksbio solvent abift of the fIuorcscenco has been found nod oxpIainod in terms af the large sotvntian energy for the Rydbarg s&to. The fhmrescenco is quenched by oxygxm, 1, Z-dichtoroethano and acctanitrile, A n