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The use of bis(aminol) ethers derived from aliphatic primary amines in the synthesis of secondary and tertiary amines

✍ Scribed by Harry Heaney; George Papageorgiou


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
829 KB
Volume
52
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES


Inside Cover: Synthesis of Primary Amine
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A striking reaction… … occurs during the splitting of secondary and tertiary amines with ammonia and the Shvo catalyst-primary amines are obtained in up to 84 % yield. More details of these fascinating reactions are discussed in the Communication by M. Beller et al. on page 4705 ff.

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At 170Β°C and using ionic liquids as solvent and catalyst, primary and secondary aliphatic amines could react with dimethyl carbonate to give alkyl carbamates with good yield. Due to its insolubility, the desired carbamate solid could be recovered by simple filtration from the two-layer mixture of di