๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Effect of dipolar aprotic solvents on the nucleophilic addition of alcohols to activated olefins

โœ Scribed by Feit, B. A.; Bigon, Z.

Book ID
126100938
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
773 KB
Volume
34
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Effect of polar aprotic solvents and org
Effect of polar aprotic solvents and organometallic catalysts on the reaction of alcohols with isocyanates
โœ S. Dabi; A. Zilkha ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 310 KB

DMF and DMSO catalyse the reaction of butanol with PhNCO but inhibit that with aliphatic isocyanates, due to formation of an active 1 : 1 charge transfer complex with the aromatic isocyanate. Similarity was found in the mode of catalysis of the urethane reaction with these solvents to that with tert