✦ LIBER ✦

Effect of curvature of the minimum energy path upon reaction dynamics: the H2O−(2B1)→H−(1S) + OH(2Π) dissociation

✍ Scribed by M. Sizun; S. Goursaud

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 528 KB
Volume: 79
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)80202-3

No coin nor oath required. For personal study only.

✦ Synopsis

The dynarmcs of the HzO-("Bt) --H-('S) + 0H(2fl) dlssoaatlon has been studled on three different potentul energ! surfaces usmg a quaslclasslcal traJectory method m the futed-angle approvlmatlon

The partltionmg of the excess energy between translatlonal and mternal ener@es of the fragments appears to be strongly affected by the curvature of the rmmmum-energy path

📜 SIMILAR VOLUMES

The OH(X2Π, υ = 0) rotational energy dis

The OH(X2Π, υ = 0) rotational energy distribution in the reaction of O(1D) + H2

✍ G.K. Smith; J.E. Butler; M.C. Lin 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 336 KB

Dynamic aspects of the reaction O(1D) +

Dynamic aspects of the reaction O(1D) + H2S → OH + SH

✍ S. Klee; K.-H. Gericke; F.J. Comes 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 297 KB

The energy disu-ibulion or nascent OH('n. v. J) produced in the reaclien o. r O('D) wilh H,S has been measured by leser-lnduccd fluorescence. The rolaGanal distributions in u"= 0 and U" -1 are Bollunannran with lemperalure paramewrs T; \_,-23C+O+IOOKand7;-\_,= 2650\*150 K A population ratio N(u"=l)/

Quasiclassical dynamical study of the re

Quasiclassical dynamical study of the reaction O(1D)+HD(1Σ+)→OD/OH(2Π)+H/D(2S) on a two-valued potential energy surface

✍ Lawrence J. Dunne 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 412 KB

## Quasiclassical trajectory calculations have been carried out for the reaction 0( 'D) +HD( 'Z\* )4OD/OH (%I) +H/D('S) using a two-valued potential energy surface derived by Murrell, Carter, Mills and Guest. The OD/OH branching ratio on this multivalued surface at 300 K is close to 2, and experim

Vibrational excitation of OH(X2Π) produc

Vibrational excitation of OH(X2Π) produced in the reaction of O(1D) with H2

✍ J.E. Butler; R.Glen MacDonald; D.J. Donaldson; J.J. Sloan 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 600 KB

A lower limit to t?re OH(X a 11) vibrational escitation produced by the reaction O(r D) + Ha has been obsewed using a low-pressure infrared chemilumiuescence anoaratus. The O(' D) was generated by laser photolysis of OS\_ The measured \_\* OH(v') vibrational distribution is inverted; it peaks at U'

Rovibronic structure and the dynamics of

Rovibronic structure and the dynamics of the predissociation processes HNO(A 1A”) →H(2S) +NO(X2Π) and HONO (Ã 1A”) →OH(X2Π) +NO(X2Π)

✍ R. N. Dixon 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 334 KB

Initial distribution of vibration of the

Initial distribution of vibration of the OH radicals produced in the H + O3 → OH(X2Π1/2,3/2) + O2 reaction. Chemiluminescence by a crossed beam technique

✍ H. Ohoyama; T. Kasai; Y. Yoshimura; H. Kimura; K. Kuwata 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 334 KB

The cherniluminescence in the H+ 0, -OH(X \*lIIW,& +O, reaction was observed uvng a crossed beam tcebnlqu& l%e tnilial population of the OH radicals tn the vibratIonal slate v (4 < u UG 9) were found to be N( 9) -1.0, N(B) -0.95&O 1, N(7) -0.9kO.2, N(6) -0 2\*0 1 and N(5) -N(4) -0 2&O 2 The IOEII cr