✦ LIBER ✦

Dynamic aspects of the reaction O(1D) + H2S → OH + SH

✍ Scribed by S. Klee; K.-H. Gericke; F.J. Comes

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 297 KB
Volume: 118
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85347-1

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✦ Synopsis

The energy disu-ibulion or nascent OH('n. v. J) produced in the reaclien o. r O('D) wilh H,S has been measured by leser-lnduccd fluorescence. The rolaGanal distributions in u"= 0 and U" -1 are Bollunannran with lemperalure paramewrs T; _,-23C+O+IOOKand7;-_,= 2650*150 K A population ratio N(u"=l)/N(u"= 0) -O-17 is observed The product-sure distribunon oker the different spm and A componenls IS statistically wllhm the experimenlal uncerminty of 20%. A compatison *JT the OH producr populations rrom the title reaction with the uell known OH yield from the O('D)+H=O reactmn shows that 25% or Lhe ~CLICLILC encounters follou the reaction channel which produca OH in u" -0 and U" = 1.

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