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Effect of Adjacent Chiral Tertiary and Quaternary Centers on the Metal-Catalyzed Allylic Substitution Reaction

✍ Scribed by Sebahar, Holly L.; Yoshida, Kazuhiro; Hegedus, Louis S.


Book ID
121455916
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
113 KB
Volume
67
Category
Article
ISSN
0022-3263

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On the Origin of Asymmetric Induction of the Palladium-Catalyzed Allylic Substitution Reaction with Chiral 4,4-Disubstituted 4,5-Dihydro-2-(phosphinoaryl)oxazole Ligands. -The configuration of the substitution product depends on the substitution pattern of the ligand which effects the orientation o