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ChemInform Abstract: On the Origin of Asymmetric Induction of the Palladium-Catalyzed Allylic Substitution Reaction with Chiral 4,4-Disubstituted 4,5-Dihydro-2-(phosphinoaryl)oxazole Ligands.

✍ Scribed by S. SCHAFFNER; J. F. K. MUELLER; M. NEUBURGER; M. ZEHNDER

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199838042

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✦ Synopsis

On the Origin of Asymmetric Induction of the Palladium-Catalyzed Allylic Substitution Reaction with Chiral 4,4-Disubstituted 4,5-Dihydro-2-(phosphinoaryl)oxazole Ligands.

-The configuration of the substitution product depends on the substitution pattern of the ligand which effects the orientation of the allylic ligand in the reaction intermediate.

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