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Effect of Adjacent Chiral Tertiary and Quaternary Centers on the Metal-Catalyzed Allylic Substitution Reaction.

✍ Scribed by Holly L. Sebahar; Kazuhiro Yoshida; Louis S. Hegedus


Book ID
111699507
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
33
Category
Article
ISSN
0931-7597

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On the Origin of Asymmetric Induction of the Palladium-Catalyzed Allylic Substitution Reaction with Chiral 4,4-Disubstituted 4,5-Dihydro-2-(phosphinoaryl)oxazole Ligands. -The configuration of the substitution product depends on the substitution pattern of the ligand which effects the orientation o