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(E)-N′-[4-(2,4-Dichlorobenzyloxy)-3-methoxybenzylidene]-2-methoxybenzohydrazide sesquihydrate

✍ Scribed by Liu, Shou-Xin ;Tian, Xia ;Zhen, Xiao-Li ;Li, Zhen-Chao ;Han, Jian-Rong


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
584 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C~23~H~20~Cl~2~N~2~O~4~·1.5H~2~O, the vanillin group makes dihedral angles of 0.52 (14) and 81.22 (7)° with the benzohydrazide residue and the dichlorobenzene ring, respectively. An intramolecular N—H...O hydrogen bond helps to stabilize the molecular conformation, while intermolecular O—H...O and bifurcated O—H...(N,O) hydrogen bonds link the molecules, forming an infinite network. One of the water molecule sites is half-occupied.


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