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2-Bromo-N′-[(E)-4-hydroxybenzylidene]-5-methoxybenzohydrazide

✍ Scribed by Sarojini, B. K. ;Narayana, B. ;Sunil, K. ;Yathirajan, H. S. ;Bolte, Michael

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
558 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The geometric parameters of the title compound, C 15 H 13 BrN 2 O 3 , are in the usual ranges. The C N double bond is trans configured. The C N-N-CO-group itself is planar, with an r.m.s. deviation of 0.044 A ˚, and makes a dihedral angle of 10.73 (19) with the hydroxyphenyl ring, but forms a dihedral angle of 67.90 (8) with the other aromatic ring. The crystal packing is stabilized by N-HÁ Á ÁO, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds.

📜 SIMILAR VOLUMES

N′-(3-Hydr­oxybenzyl­idene)-2-methoxyben
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2-Bromo-5-methoxybenzohydrazide
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In the title compound, C~8~H~9~BrN~2~O~2~, the amide bond is in a __cis__ configuation. The N—N—C=O group is planar [torsion angle 0.6 (6)°] and forms a dihedral angle of 46.4 (2)° with the aromatic ring. The crystal packing is stabilized by two strong and one rather weak N—H...O hydrogen bonds.

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✍ Tang, Chun-Bao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 415 KB

The title Schiff base compound, C 13 H 10 BrN 3 O 2 , was derived from the condensation reaction of salicylaldehyde with 5bromonicotinohydrazide. The dihedral angle between the benzene ring and the pyridine ring is 13.2 (4) . In the crystal structure, molecules are linked through N-HÁ Á ÁO and C-HÁ