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(E)- and (Z)-1-Hydroxy-1,3-butadiene: new kinetically unstable C4H6O isomers

โœ Scribed by Turecek, Frantisek; Havlas, Zdenek; Maquin, Francis; Hill, Nicholas; Gaeumann, Tino


Book ID
127115700
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
661 KB
Volume
51
Category
Article
ISSN
0022-3263

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The mass spectra of organic compounds. 8
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The unstable neutral enol, 1-buten-3-yn-2-01, and its deuterium-labelled analogues were generated in the gas phase by high-vacuum flash pyrolysis of the corresponding 2-ex0 -ethynylnorborn-5-en-2-01~, or alternatively from 1-ethynylcyclobutdnol. The ionization energy of the enol was measured as 8.92

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Hydrazones of some saccharides exhibit significant biological activities. They inhibit nucleo-and proteo-synthesis in tumorous cells' and the growth of bacteria3. Hydrazones of monosaccharides generally crystallize well, and they are useful derivatives for the identification4 and isolation of reduci