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Synthesis of the E and Z isomers of 1,3,4,5,6-penta-O-acetyl-keto-d-fructose (2,4-dinitrophenyl)hydrazone

✍ Scribed by Kazimír Linek; Juraj Alföldi; Štefan Kučár; Tibor Sticzay; Zlatica Novotná; Biserka Kojić-Prodić

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
364 KB
Volume
115
Category
Article
ISSN
0008-6215

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✦ Synopsis

Hydrazones of some saccharides exhibit significant biological activities. They inhibit nucleo-and proteo-synthesis in tumorous cells' and the growth of bacteria3. Hydrazones of monosaccharides generally crystallize well, and they are useful derivatives for the identification4 and isolation of reducing carbohydrates'.

Much attention has been paid to study of the structure of hydrazones, both cyclic and acyclic. The structure of hydrazones can be determined by several methods. For crystalline compounds, the most convenient method is X-ray crystal-structure analysis. By this method, the cyclic structure of D-arabinose (4-bromophenyl)hydra-

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