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An improved synthesis of 1,2,3,4,6-Penta-O-Acetyl-5-Deoxy-5-C-[(R,S)-ethylphosphinyl]-α,β-d-glucopyranoses, and formation of 2,3,4,6-Tetra-O-acetyl-1,5-anhydro-5-deoxy-5-C-[(R)-Ethylphosphinyl]-d-glucitol

✍ Scribed by Hiroshi Yamamoto; Hiroshi Murata; Saburo Inokawa; Mitsuji Yamashita; Margaret-Ann Armour; Thomas T. Nakashima

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
417 KB
Volume
133
Category
Article
ISSN
0008-6215

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We have previously reported' the synthesis of 1,2,3-tri-O-acetyGI,Sdideoxy-4-C-[(R,S)-phenylphosphinyl] -o&3-D-ribo-and -L-lyxo-furanoses (4) by the sequence of 1 -+ 2 + 3 + 4. However, this method could not be applied to a synthesis of 4deoxy-\*To whom correspondence may be addressed.