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(E)-4-(p-Tolyl­diazen­yl)phenol

✍ Scribed by Petek, Hande ;Erşahin, Ferda ;Albayrak, Çiğdem ;Ağar, Erbil ;Şenel, İsmet


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
220 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 13 H 12 N 2 O, consisting of two aromatic groups linked through a diazene bridge, exhibits trans geometry with respect to the azo double bond and deviates slightly from planarity. The crystal structure is stabilized by intermolecular O-HÁ Á ÁN hydrogen bonds.


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The molecule of the title compound, C 14 H 12 N 2 O 2 , is nearly planar and displays a trans configuration with respect to the N N double bond, as found for other diazene derivatives. There is an intramolecular O-HÁ Á ÁO hydrogen bond and the crystal packing is governed bystacking.

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In the title compound, C~15~H~15~ClN~2~O, the aromatic rings adopt a __trans__ configuration with respect to the N=N bond, as found for other diazene derivatives. The crystal structure is stabilized by intermolecular O—H...N hydrogen bonds, forming a polymeric chain along the __c__ axis.

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In the title structure, C 14 H 11 N 2 O 2 Cl, the benzene rings are in a trans configuration with respect to the azo double bond and the molecule is essentially planar.