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(E)-2-Acetyl-4-[(3-chloro­phen­yl)diazen­yl]phenol

✍ Scribed by Özdemir, Gonca ;Işık, Şamil ;Albayrak, Çiğdem ;Ağar, Erbil


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
216 KB
Volume
62
Category
Article
ISSN
1600-5368

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(E)-4-[(4-Chloro­phen­yl)diazen­yl]-2-is
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In the title compound, C~15~H~15~ClN~2~O, the aromatic rings adopt a __trans__ configuration with respect to the N=N bond, as found for other diazene derivatives. The crystal structure is stabilized by intermolecular O—H...N hydrogen bonds, forming a polymeric chain along the __c__ axis.

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diazenyl]phenol O ¨zdemir Gonca, a Is ¸ık S ¸amil, a C ¸ig ˘dem Albayrak b and Ag ˘ar Erbil b \*

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The molecule of the title compound, C 14 H 12 N 2 O 2 , is nearly planar and displays a trans configuration with respect to the N N double bond, as found for other diazene derivatives. There is an intramolecular O-HÁ Á ÁO hydrogen bond and the crystal packing is governed bystacking.

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The principal molecule of the title molecule, C 12 H 8 -ClN 3 O 3 ÁC 3 H 7 NO, is essentially planar. The two benzene rings make a dihedral angle of only 6.9 (1) . The nitro group is slightly twisted with respect to the benzene ring to which it is attached [3.7 ( 1) ]. The dimethylformamide solvent

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In the title structure, C 14 H 11 N 2 O 2 Cl, the benzene rings are in a trans configuration with respect to the azo double bond and the molecule is essentially planar.

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