In the title compound, C~15~H~15~ClN~2~O, the aromatic rings adopt a __trans__ configuration with respect to the N=N bond, as found for other diazene derivatives. The crystal structure is stabilized by intermolecular O—H...N hydrogen bonds, forming a polymeric chain along the __c__ axis.
(E)-2-Acetyl-4-[(3-chlorophenyl)diazenyl]phenol
✍ Scribed by Özdemir, Gonca ;Işık, Şamil ;Albayrak, Çiğdem ;Ağar, Erbil
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 216 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
diazenyl]phenol O ¨zdemir Gonca, a Is ¸ık S ¸amil, a C ¸ig ˘dem Albayrak b and Ag ˘ar Erbil b \*
The molecule of the title compound, C 14 H 12 N 2 O 2 , is nearly planar and displays a trans configuration with respect to the N N double bond, as found for other diazene derivatives. There is an intramolecular O-HÁ Á ÁO hydrogen bond and the crystal packing is governed bystacking.
The principal molecule of the title molecule, C 12 H 8 -ClN 3 O 3 ÁC 3 H 7 NO, is essentially planar. The two benzene rings make a dihedral angle of only 6.9 (1) . The nitro group is slightly twisted with respect to the benzene ring to which it is attached [3.7 ( 1) ]. The dimethylformamide solvent
In the title structure, C 14 H 11 N 2 O 2 Cl, the benzene rings are in a trans configuration with respect to the azo double bond and the molecule is essentially planar.
In the title structure, C 16 H 16 N 2 O 3 , the benzene rings are in a trans configuration with respect to the azo double bond and the molecule is essentially planar.