In the title compound, C~13~H~10~N~4~O~5~·C~3~H~7~NO, the Schiff base is approximately planar. Molecules are connected __via__ weak intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds.
4-[(2-Chloro-4-nitrophenyl)diazenyl]phenol dimethylformamide solvate
✍ Scribed by You, Xiu-Li ;Zhang, Yan ;Zhang, Yong ;Zhang, De-Chun
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 229 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The principal molecule of the title molecule, C 12 H 8 -ClN 3 O 3 ÁC 3 H 7 NO, is essentially planar. The two benzene rings make a dihedral angle of only 6.9 (1) . The nitro group is slightly twisted with respect to the benzene ring to which it is attached [3.7 ( 1) ]. The dimethylformamide solvent molecule and the azobenzene molecule are linked through a strong O-HÁ Á ÁO hydrogen bond. In the crystal structure, the molecules are stacked throughinteractions along [010]. Some weak C-HÁ Á ÁO interactions stabilize the packing.
📜 SIMILAR VOLUMES
In the title compound, C~15~H~15~ClN~2~O, the aromatic rings adopt a __trans__ configuration with respect to the N=N bond, as found for other diazene derivatives. The crystal structure is stabilized by intermolecular O—H...N hydrogen bonds, forming a polymeric chain along the __c__ axis.
diazenyl]phenol O ¨zdemir Gonca, a Is ¸ık S ¸amil, a C ¸ig ˘dem Albayrak b and Ag ˘ar Erbil b \*
In the title molecule, C~17~H~10~F~5~N~5~O~2~, all bond lengths and angles show normal values. Weak intermolecular C—H...O hydrogen bonds and π–π stacking interactions stabilize the crystal packing.