4-Chloro-2-(p-tolyliminomethyl)phenol
✍ Scribed by Zhang, Xin-Li ;Li, Zong-Xiao
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 91 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 14 H 12 N 2 O 4 , exists as an enol-imine tautomer, in which a strong intramolecular O-HÁ Á ÁN hydrogen bond is formed. This study verifies the preference of the enol-imine tautomeric form in the solid state.
The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b
The title compound, [Fe(C 5 H 5 )(C 18 H 12 Cl 2 N)], a new Schiff base containing a ferrocenyl (Fc) group, has been synthesized and characterized structurally. The compound is a trans isomer. The C Fc -C-N-C linkage has a near-planar geometry, indicating conjugation. There are no obvious intermolec