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1-[(2-Chloro­phen­yl)(4-chloro­phenyl­imino)meth­yl]ferrocene

✍ Scribed by Zhang, Yan ;Gao, Wen-Yuan ;Chen, Hai-Xia

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
129 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Fe(C 5 H 5 )(C 18 H 12 Cl 2 N)], a new Schiff base containing a ferrocenyl (Fc) group, has been synthesized and characterized structurally. The compound is a trans isomer. The C Fc -C-N-C linkage has a near-planar geometry, indicating conjugation. There are no obvious intermolecular interactions.

📜 SIMILAR VOLUMES

1-{(2-Chloro­phen­yl)[(4-methyl­phen­yl)
1-{(2-Chloro­phen­yl)[(4-methyl­phen­yl)imino]meth­yl}ferrocene
✍ Wang, Hong-Xing ;Zhou, Hui-Chao ;Wu, Hong-Fei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 127 KB

The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.

3-[β-(4-Chloro­phen­yl)-α-(4-methoxy­phe
3-[β-(4-Chloro­phen­yl)-α-(4-methoxy­phen­yl)vin­yl]-2-meth­yl-1-phenyl­sulfon­yl-1H-indole
✍ Usha, G. ;Selvanayagam, S. ;Velmurugan, D. ;Ravikumar, K. ;Jaisankar, P. ;Sriniv 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 359 KB

In the title compound, C 30 H 24 ClNO 3 S, the phenylsulfonyl, chlorophenyl and methoxyphenyl rings are each almost perpendicular to the indole ring system. The crystal packing shows centrosymmetrically related pairs of molecules. Intermolecular C-HÁ Á ÁO interactions are present.

4-{[3-(2-Chloro­phen­yl)-1,2,4-oxadiazol
4-{[3-(2-Chloro­phen­yl)-1,2,4-oxadiazol-5-yl]meth­yl}-1-[(2,6-dimethyl­phen­yl)amino­carbon­yl­meth­yl]piperazine
✍ Wang, Hai-Bo ;Pu, Yue-Qing ;Chen, Jia-Hui ;Wang, Jin-Tang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

The title compound, C 23 H 26 ClN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 5-chloromethyl-3-(2-chlorophenyl)-1,2,4oxadiazole. In the structure, there are intramolecular C-HÁ Á ÁN, N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds, and intermolecular