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2-[Bis(4-methoxy­phen­yl)meth­yl]benz­yl chloro­acetate

✍ Scribed by Jones, Peter G. ;Kuś, Piotr ;Łapok, Łukasz

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
148 KB
Volume
61
Category
Article
ISSN
1600-5368

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In the title compound, C 16 H 13 ClN 2 O 2 , the dihedral angle between the pyridine and benzene rings is 40.1 (1) . There is a weak intramolecular C-HÁ Á ÁCl interaction. Molecules are linked via O-HÁ Á ÁN hydrogen bonds, forming chains of graph-set motif C(6) along the a axis.

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The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.

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In the structure of the title compound, C 10 H 9 ClN 2 O 2 , there is a weak intramolecular C-HÁ Á ÁN interaction, and intermolecular C-HÁ Á ÁO and C-HÁ Á ÁN interactions.

3-[β-(4-Chloro­phen­yl)-α-(4-methoxy­phe
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In the title compound, C 30 H 24 ClNO 3 S, the phenylsulfonyl, chlorophenyl and methoxyphenyl rings are each almost perpendicular to the indole ring system. The crystal packing shows centrosymmetrically related pairs of molecules. Intermolecular C-HÁ Á ÁO interactions are present.