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Dynamic spin crossover in [Fe(2-BIK)3](ClO4)2 and [Fe(Me22-BIK)3](BF4)2 investigated by Mössbauer spectroscopy

✍ Scribed by A. Bousseksou; C. Place; J. Linares; F. Varret


Book ID
113317008
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
133 KB
Volume
104-107
Category
Article
ISSN
0304-8853

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The reaction of Fe(BF 4 ) 2 •6H 2 O and one equivalent of HC(3,5-Me 2 pz) 3 in acetonitrile leads to the formation of {Fe[HC(3,5-Me 2 pz) 3 ](H 2 O) 3 }(BF 4 ) 2 . The solution phase 1 H NMR spectrum is broad with chemical shifts ranging from 54 to -42 ppm, a range that is indicative of a paramagnet