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Structural, Electronic, and Magnetic Properties of {Fe[HC(3,5-Me 2 pz) 3 ] 2 }(BF 4 ) 2 (pz = Pyrazolyl): Observation of Unusual Spin-Crossover Behavior

✍ Scribed by Reger, Daniel L.; Little, Christine A.; Rheingold, Arnold L.; Lam, Matthew; Concolino, Tom; Mohan, Amitabh; Long, Gary J.


Book ID
120626917
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
39 KB
Volume
39
Category
Article
ISSN
0020-1669

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Synthesis, solid-state structure, magnet
✍ Daniel L. Reger*; Christine A. Little; Arnold L. Rheingold; Roger Sommer; Gary J 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 133 KB

The reaction of Fe(BF 4 ) 2 •6H 2 O and one equivalent of HC(3,5-Me 2 pz) 3 in acetonitrile leads to the formation of {Fe[HC(3,5-Me 2 pz) 3 ](H 2 O) 3 }(BF 4 ) 2 . The solution phase 1 H NMR spectrum is broad with chemical shifts ranging from 54 to -42 ppm, a range that is indicative of a paramagnet