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Structural Correlations in High-Spin Complexes of [Fe{HC(3,5-Me2pz)3}2]2+: Solid State Structure of [Fe{HC(3,5-Me2pz)3}2][Fe2OCl6]

✍ Scribed by Daniel L. Reger; Mark D. Smith; Kenneth J. Brown


Book ID
106404305
Publisher
Springer
Year
2009
Tongue
English
Weight
198 KB
Volume
39
Category
Article
ISSN
1572-8854

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Synthesis, solid-state structure, magnet
✍ Daniel L. Reger*; Christine A. Little; Arnold L. Rheingold; Roger Sommer; Gary J 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 133 KB

The reaction of Fe(BF 4 ) 2 •6H 2 O and one equivalent of HC(3,5-Me 2 pz) 3 in acetonitrile leads to the formation of {Fe[HC(3,5-Me 2 pz) 3 ](H 2 O) 3 }(BF 4 ) 2 . The solution phase 1 H NMR spectrum is broad with chemical shifts ranging from 54 to -42 ppm, a range that is indicative of a paramagnet