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Synthesis, Crystal Structure, Magnetic Properties and 57Fe Mössbauer Spectroscopy of the New Trinuclear [Fe3(4-(2′-hydroxyethyl)-1,2,4-triazole)6(H2O)6](CF3SO3)6 Spin Crossover Compound

✍ Scribed by Yann Garcia; Philippe Guionneau; Georges Bravic; Daniel Chasseau; Judith A. K. Howard; Olivier Kahn; Vadim Ksenofontov; Sergei Reiman; Philipp Gütlich


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
376 KB
Volume
2000
Category
Article
ISSN
1434-1948

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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =