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Dynamic-mechanical study of water-blown rigid polyurethane foams with and without soy flour

✍ Scribed by Li-Chung Chang; Yu Xue; Fu-Hung Hsieh


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
178 KB
Volume
81
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Glass transition temperatures of water‐blown rigid polyurethane foams at three levels of initial water content, 4.5–5.5%, and five levels of soy flour, 0–40%, were determined by dynamic‐mechanical instrumentation at the temperature range of 50–280Β°C and the frequencies from 0.1 to 20 Hz. The results showed that both the addition of soy flour in the rigid polyurethane foam system and increasing initial water content contributed to a higher glass transition temperature. Moreover, increasing the percentage of the soy flour in the rigid polyurethane foam system led to higher compressive strength and broader master curves for the imaginary part of the elastic modulus. The KWW function fitted the master curve better than the HN and CD functions. Β© 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2027–2035, 2001


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## Abstract Rigid polyurethane foams (PUFs) were prepared from polymeric 4,4‐diphenylmethane diisocyanate (PMDI; having functionality of 2.9), polyether polyols, silicone surfactant, amine catalysts, and distilled water. The effects of reactivity on the properties such as density, compressive and f