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Dynamic kinetic resolution of racemic α-halo acids via a chiral imidazolidinone auxiliary

✍ Scribed by Jeff A. O'Meara; Manfred Jung; Tony Durst

Book ID: 103404970
Publisher: Elsevier Science
Year: 1995
Tongue: French
Weight: 196 KB
Volume: 36
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(95)00339-e

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Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. -The title compounds (IV), precursors of synthetically important Reetz aldehydes, are prepared by highly diastereoselective amination of α-bromo esters (I). The high yields obtained in this amin