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Dye-sensitized photo-oxygenation of tryptophan

✍ Scribed by Masako Nakagawa; Yukio Yokoyama; Shiro Kato; Tohru Hino

Book ID
108374429
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
867 KB
Volume
41
Category
Article
ISSN
0040-4020

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✍ Charles W. Jefford; AndrΓ© F. Boschung πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 French βš– 172 KB

The mechanistically interesting claim was recently made that the dyesensitized photo-oxygenation of biadmantylidene (1) in pinacolone as solvent gave the corresponding dioxetane (2) and epoxide (2) while solvent was converted to t-butyl acetate.' This result was interpreted as proof that a perepoxi