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Formation of 1,4-endoperoxides from the dye-sensitized photo-oxygenation of alkyl-naphthalenes

✍ Scribed by Wasserman, Harry H.; Larsen, David L.


Book ID
121193581
Publisher
The Royal Society of Chemistry
Year
1972
Tongue
English
Weight
192 KB
Volume
5
Category
Article
ISSN
0022-4936

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The dye-sensitized photo-oxygenation of
✍ Charles W. Jefford; AndrΓ© F. Boschung πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 French βš– 172 KB

The mechanistically interesting claim was recently made that the dyesensitized photo-oxygenation of biadmantylidene (1) in pinacolone as solvent gave the corresponding dioxetane (2) and epoxide (2) while solvent was converted to t-butyl acetate.' This result was interpreted as proof that a perepoxi