Kinetic aspects of dye-sensitized photo-oxygenation
β Scribed by D. Brkic; P. Forzatti; I. Pasquon; F. Trifiro
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 774 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0047-2670
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The mechanistically interesting claim was recently made that the dyesensitized photo-oxygenation of biadmantylidene (1) in pinacolone as solvent gave the corresponding dioxetane (2) and epoxide (2) while solvent was converted to t-butyl acetate.' This result was interpreted as proof that a perepoxi
In connection with the interesting behavior of the dye-sensitized photooxygenation of various N-heterocycles 1 and seven-membered conjugated trienes such as cycloheptatrienes 2 and tropolones,' . it seemed of general interest to examine such reaction of aza-cycloheptatrienes, e.g., azepines and diaz