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Drop flash chemiluminescence in the reaction of W(CO)6with XeF2

✍ Scribed by R. G. Bulgakov; S. P. Kuleshov; G. A. Tolstikov; V. P. Kazakov

Book ID: 112444550
Publisher: Springer
Year: 1986
Tongue: English
Weight: 77 KB
Volume: 35
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00953264

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## Abstract The reaction Cl + H~2~CO → HCl + HCO has been studied at 295 K. Chlorine atoms were produced via the infrared laser induced dissociation of CCl~3~F, using a pulsed CO~2~ TEA laser. Using HCl infrared chemiluminescence as the diagnostic, we find the rate constant to be 7.4 ± 0.7 × 10^−11