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Drop flash chemiluminescence in the reaction of W(CO)6with XeF2

โœ Scribed by R. G. Bulgakov; S. P. Kuleshov; G. A. Tolstikov; V. P. Kazakov


Book ID
112444550
Publisher
Springer
Year
1986
Tongue
English
Weight
77 KB
Volume
35
Category
Article
ISSN
1573-9171

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## Abstract The reaction Cl + H~2~CO โ†’ HCl + HCO has been studied at 295 K. Chlorine atoms were produced via the infrared laser induced dissociation of CCl~3~F, using a pulsed CO~2~ TEA laser. Using HCl infrared chemiluminescence as the diagnostic, we find the rate constant to be 7.4 ยฑ 0.7 ร— 10^โˆ’11