Redox reactions in the XeF2/platinum flu
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Neil Bartlett; Boris αΊemva; Lionell Graham
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Article
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1976
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Elsevier Science
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English
β 781 KB
Liquid XeF2 at 140-150' oxidizes PtF4: 5XeF2 f 2PtF4 -2Xe2F3PtF6 + Xe f. The salt Xe2F3+PtF6-loses XeF2 at 70" in vacua: --Xe2F3PtF6-XeFPtF6 + XeF2 f. Pyrolysis of XeF+PtF6at 150-160" yields XeF4: XeFPtF6 -XePt2FlO + XeF4 f. The complex XePt2F10 loses XeF2 at 430": XePt2FlO +PtF4 + XeF2 +. XePt2Flo